This paper introduces a nitrogen-doped ordered mesoporous carbon (NOMC) derived from glucosamine with hybrid capacitive behaviors, achieved by successfully combining electri-cal double-layer capacitance with pseudo-capacitance behaviors. The nitrogen doping con-tent of the fabricated NOMC reached 7.4 at% while its specific surface area (SBET) and total pore volume reached 778 m2 g−1 and 1.17 cm3 g−1, respectively. A dual mesoporous structure with small mesopores centered at 3.6 nm and large mesopores centered at 9.9 nm was ob-served. The specific capacitance of the reported materials reached up to 328 F g−1, which was 2.1 times higher than that of pristine CMK-3. The capacitance retention rate was found to be higher than 87.9% after 1000 charge/discharge cycles. The supplementary pseudo-capacitance as well as the enhanced wettability and conductivity due to the incorporation of nitrogen heteroatoms within the carbon matrixes were found to be responsible for the excel-lent capacitive performance of the reported NOMC materials.